The Effect of Ni/Co Ratio on the Morphology and OER Performance of NiCo-LDH/NF

The Effect of Ni/Co Ratio on the Morphology and OER Performance of NiCo-LDH/NF

Authors

  • Zhicong Yuan Xi’an Shiyou University, School of Materials Science and Engineering, Xian 710065, China

DOI:

https://doi.org/10.53469/wjimt.2025.08(04).20

Keywords:

Layered double hydroxide, Self-supporting electrode, Electrocatalysis, Oxygen evolution reaction

Abstract

Electrochemical water splitting is a promising technology for the sustainable conversion, storage and transport of hydrogen energy. Finding earth-abundant, highly active and durable oxygen evolution reaction (OER) electrocatalysts to replace precious metal-based catalysts is of great significance for the large-scale application of water electrolysis. Designing electrodes with a large number of active sites and high specific surface area is an effective strategy to improve electrocatalytic performance. In this paper, a series of NiCo-LDH/NF catalysts with different nanoneedle morphologies were prepared by a simple hydrothermal method on a nickel foam (NF) conductive substrate by adjusting the molar ratio of nickel to copper (2:4, 4:4 and 8:4 mmol). The combination of layered double hydroxide (NiCo-LDH) and NF can ensure a larger active area and provide an effective new way for electron transfer. The formed self-supporting electrode has better OER performance. This work provides new insights into OER under alkaline conditions.

References

Oh J-H, Lee Y H, Kim M, et al. Evaluation of thermal plasma-synthesized cobalt boride nanoparticles as efficient water-splitting catalysts[J]. Journal of Environmental Chemical Engineering, 2023, 11(2): 109578.

Dong Y, Liu Q, Qi C, et al. Surface nitriding to improve the catalytic performance of FeNi3 for the oxygen evolution reaction[J]. Chemical Communications, 2022, 58(90): 12592-12595.

Avani A V, Anila E I. Recent advances of MoO3 based materials in energy catalysis: applications in hydrogen evolution and oxygen evolution reactions[J]. International Journal of Hydrogen Energy, 2022, 47(47): 20475-20493.

Haase F T, Rabe A, Schmidt F-P, et al. Role of nanoscale inhomogeneities in Co2FeO4 catalysts during the oxygen evolution reaction[J]. Journal of the American Chemical Society, 2022, 144(27): 12007-12019.

Tan Y, Xu X, Li Q, et al. Constructing ultrathin FeS/FeOxH@Fe nano-sheets for highly efficient oxygen evolution reaction[J]. Journal of Colloid and Interface Science, 2021, 594: 575-583.

Bai L, Hsu C-S, Alexander D T L, et al. A cobalt-iron double-atom catalyst for the oxygen evolution reaction[J]. Journal of the American Chemical Society, 2019, 141(36): 14190-14199.

Li Y, Zhang X, Zhuo S, et al. Flower-like CoO@Cu2S nanocomposite for enhanced oxygen evolution reaction[J]. Applied Surface Science, 2021, 555: 149441.

Hou J, Yuan M, Grigoriev S A, et al. NiCo-sulfide hetero-structured interface induced highly active nickel-dominated metal sites for oxygen evolution reaction[J]. International Journal of Hydrogen Energy, 2022, 47(50): 21352-21360.

Dang H F, Dong X F, Dong Y C, et al. TiO2 nanotubes coupled with nano-Cu(OH)2 for highly efficient photocatalytic hydrogen production[J]. International Journal of Hydrogen Energy, 2013, 38(5): 2126-2135.

Zhou S H, Feng X, Shi H Y, et al. Direct growth of vertically aligned arrays of Cu(OH)2 nanotubes for the electrochemical sensing of glucose[J]. Sensors and Actuators B: Chemical, 2013, 177: 445-452.

Zhe T T, Sun X Y, Liu Y N, et al. An integrated anode based on porous Ni/Cu(OH)2 nanospheres for non-enzymatic glucose sensing[J]. Microchemical Journal, 2019, 151: 104197.

Liu H, An S L, Han X X, et al. 3D heterostructure of 2D Y-doped Cu(OH)2 nanosheet supported by nickel foam as advanced electrodes for high performance supercapacitor[J]. Vacuum, 2021, 187: 110106.

Xiong D, Li W, Liu L. Vertically aligned porous nickel(II) hydroxide nanosheets supported on carbon paper with long-term oxygen evolution performance[J]. 2017, 12(5): 543-551.

Cao L M, Cao Q C, Zhang J, et al. Electrochemically controlled synthesis of ultrathin nickel hydroxide nanosheets for electrocatalytic oxygen evolution[J]. Inorganic Chemistry, 2021, 60(5): 3365-3374.

Duan J J, Chen S, Zhao C. Ultrathin metal-organic framework array for efficient electrocatalytic water splitting[J]. Nature Communications, 2017, 8(1): 15341.

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Published

2025-04-28

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